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Info_Description
:HDMEDIAPATH
System
System
Arial
ASYM_AutoHotwords
false
info_LastSavedBy
09/11/97 15:49:07 PM
info_LastSaved
<auto>
:CDMEDIAPATH
alfon
System
<BookPath>
false
45:38 PM
ASYM_LogEncrypt
<auto>
ASYM_LogName
Arial
Arial
<auto>
ASYM_LogAppend
Info_Title
ASYM_FullScreen
Copyright - Environment Canada 1997
Arial
false
09/11/97 15:48:44 PM
glossary.tbk
Efraim Halfon
ASYM_AuthorResetPrompt
Arial
Times New Roman
Times New Roman
Times New Roman
Arial
Arial
System
Arial
System
Arial
false
30:35 PM
Arial
ASYM_AutoGlossary
Efraim Halfon
Arial
Arial
Arial
Arial
Arial
Arial
Symbol
System
Arial
Arial
Times New Roman
Arial
MS Sans Serif
palatia
Arial
Arial MT
<BookPath>
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Arial MT
Arial MT
Arial MT
Arial
s Serif
	YM_AutoHotwords
<auto>
Times New Roman
Times New Roman
Arial MT
Arial
s Serif
The Osprey
Efraim Halfon
anypage
ge "ospcb"
osprey
justincase
welcome
Page "welcome"
osdde
ostcdd
os005
osddea
welcome
os008
os010
os001
second page
os011
os002
os006
os012
osunits
osunitsa
save page
os003
os013
ospcb
ospcba
os004
title
oslit
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os014
oshga
oslita
osunits
save page
toxics
welcome
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title
q970321135740260351820
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noscrollup
noscrolldown
arrow
left arrow
xxxxp
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wwwwwwp
wwwwwww
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wwwwwwwww
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wwwwwww
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wwwww
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ppppp
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xxxxp
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&File
&Open...	Ctrl+O
&Save	Ctrl+S
Save &As...
saveas
&Import...
import
&Export...
export
Print Set&up...
printsetup
&Print Pages...	Ctrl+P
printpages
Prin&t Report...
printreport
Send &Mail...
sendmail
&Run...
E&xit	Alt+F4
&Edit
&Undo	Ctrl+Z
Cu&t	Ctrl+X
&Copy	Ctrl+C
&Paste	Ctrl+V
paste
C&lear	Del
clear
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selectall
Select Pa&ge	Shift+F12
selectpage
&Size to Page	F11
sizetopage
F&ind...	F5
Re&place...
replace
Aut&hor	F3
author
&Text
&Character...	F6
character
&Paragraph...	F7
paragraph
&Regular	Ctrl+Space
regular
&Bold	Ctrl+B
&Italic	Ctrl+I
italic
&Underline	Ctrl+U
underline
Stri&keout	Ctrl+K
strikeout
Superscrip&t/Subscript
superscriptSubscript
&Normal Script
normalscript
Su&bscript	Ctrl+L
subscript
Su&perscript	Ctrl+Shift+L
superscript
&Show Hotwords	F9
showhotwords
&Page
&Next	Alt+Right
&Previous	Alt+Left
previous
&First	Alt+Up
first
&Last	Alt+Down
&Back	Shift+F2
&History...	Ctrl+F2
history
N&ew Page	Ctrl+N
newpage
&Help
&Contents	F1
contents
Status &Bar	F12
statusbar
stagePageBackground
welcome
fullScreen
Reader
stagePageBackground
welcome
editScreen
stopTimer
Author
discover
enterBook
.'+	+F
false
ASYM_HyperPath
&ASYM_AutoHotwords
\!ASYM_AutoGlossary
enterPage
.'+	+F
leavePage
reader
|initializeSystemVariables
ASYM_HyperPath
&ASYM_AutoHotwords
editScreen
fullScreen
author
enterApplication
.'+	+F
button
mouseLeave
.'+	+F
.'+	+F
button
slide
mouseEnter
.'+	+F
Button
buttonClick
.'+	+F
rightButtonUp
myPath
state\
mediaLocation
driveName
CD_drive
editScreen
fullScreen
SCD_drive
9checkDisplaySystem
myPath
initializeSystemVariables
screenXpixels
TB40WIN.DLL
DisplayBitsPerPixel
TB40WIN
horizontalDisplayRes,verticalDisplayRes
9verticalDisplayRes
tb40win.dll
rpDisplayBitsPerPixel
pixelDepth
screenYpixels
horizontalDisplayRes
verticalDisplayRes
horizontalDisplayRes
Sorry! Your system needs an upgraded video card to use this CD-ROM.
checkDisplaySystem
ate\"
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/<> "welcome") 
/<> "stagePageBackground") 
fullScreen 
Author
/<> "
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editScreen 
stopTimer(0)
palette 
"discover"
isObject (
914,705,8534,5490
J"show1" 
756,600,8661,6285
B"up" 
4129,5628,4714,6003
B"down" 
5164,5628,5749,6003
B"backtrack" 
3887,6466,6932,6796
2667,6466,3222,6976
ASYM_HyperPath 
ASYM_AutoHotwords 
ASYM_AutoGlossary 
targetWindow = 
	mmClose 
---Intilization handlers 
the startup up 
enterApplication
initializeSystemVariables
enabled 
x"slide"
o= 44
buttonClick
mediaLocation
	-- You should 
a correct location 
CD-ROM here.
myPath
 & "state\"
CD_drive
driveName = 
statusBar
captionBar 
= thickFrame
s970124.tbk"
0 = thinFrame
 = It & ":\"
checkDisplaySystem
screenXpixels
screenYpixels
pixelDepth
	linkDLL "TB40WIN.
		INT horizontalDisplayRes()
verticalDisplayRes()
8es()
	unlinkDLL functions "
tb40win.dll"
DisplayBitsPerPixel()
"Sorry! Your 
4needs 
upgraded video card 
CD-ROM." 
f"OK"
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discover
osfig12
osfig01
osfig02
osfig05
osfig13
osfig03
sd022
osfig06
osfig08
osfig09
osfig11
osfig12
osfig10
osfig07
befig01
osfig04
state\figures\osfig12.bmp
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state\figures\osprey1b.bmp
state\figures\osfig05.bmp
state\figures\osfig13.bmp
state\figures\osprey3.bmp
state\figures\osprey3.bmp
state\figures\osprey4.bmp
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state\figures\osfig11.bmp
state\figures\osfig12.bmp
state\figures\osprey7.bmp
state\figures\osfig07.bmp
state\figures\befig01.bmp
state\figures\sd022.bmp
scroll up
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Quit Now
hide stage
close this window
save page
tbk_backdrop
buttonClick
buttonStillDown
enterPage
reader
buttonClick
" <> 0
" - 1
		enabled 
B"down" 
textUnderFlow 
" = 0
notifyBefore 
" = 0
" = 0
buttonClick
buttonStillDown
enterPage
reader
buttonClick
textOverFlow 
" = 0
		enabled 
" + 1
B"up" 
notifyAfter 
" = 0
" = 0
buttonClick
buttonClick
close 
welcome
buttonClick
buttonClick
stage "welcome"
mmClose All
buttonClick
buttonClick
enterpage
moved
tbk_reset
buttonDown
buttonUp
buttonClick
buttonDoubleClick
rightButtonDown
rightButtonUp
rightButtonClick
rightButtonClick
rightButtonDoubleClick
-- This 
was added 
your 
Hthe MTB40.SBK sysbook
-- It 
used 
define 
'behavior 
backdrops
notifybefore 
"0,0"
"0,0" 
moved
	ssm = sysSuspendMessages
notifyBefore tbk_reset
buttonClick 
rightButtonClick 
.'+	+F
Save this screen in file
Page added to file 
Could not create file
Could not write to 
save page
c:\grtlakes.doc
buttonClick
buttonClick
"="" 
---		
"title" 
fileName
 = "c:\grtlakes.doc"
("Save 
screen 
	--Checks that the 
pexists 
can be opened
		--If 
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5, create 
(which also opens 
"Could 
" && 
 & "."
xwrite 
"Page added 
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*ClassEntry*
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*WINDOWSEG*
*ICONRESTAB*
*ICONRESSEG*
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Background
*OBJTABLE*
*IDTABLE*
*NAMETAB*
Rectangle
Ellipse
RoundedRectangle
Polygon
IrregularPolygon
AngledLine
Curve
PaintObject
Picture
Group
Stage
Button
Viewer
ComboBox
Field
RecordField
Hotword
*RHOTWORD*
*TbxBase*
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bxBase*
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title
.'+	+F
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buttonClick
buttonClick
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currentPage 
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Historical Records
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buttonClick
buttonClick
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buttonClick
buttonClick
"osprey"
currentPage 
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%modal
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os007
osprey
buttonClick
buttonClick
"osprey"
currentPage 
"os007" 
%modal
Eggshell Thinning
.'+	+F
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os006
osprey
buttonClick
buttonClick
"osprey"
currentPage 
"os006" 
%modal
Effects of Organochlorine Pesticides
.'+	+F
.'+	+F
os005
osprey
buttonClick
buttonClick
"osprey"
currentPage 
"os005" 
%modal
Reproductive Problems
.'+	+F
.'+	+F
os010
osprey
buttonClick
buttonClick
"osprey"
currentPage 
"os010" 
%modal
Recovery
buttonClick
buttonClick
More ...     About Ospreys
continue
buttonClick
buttonClick
close 
Backtrack
.'+	+F
.'+	+F
osprey
os012
buttonClick
buttonClick
"osprey"
currentPage 
"os012" 
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title
970304083046862929161214522
ASYM_TpID
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Osprey and Toxic Contaminants - I
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Toxic Contaminants
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os001
The Osprey (Pandion haliaetus) was once common along shallow water 
margins of the Great Lakes. A hundred years ago James Henry Fleming, a famous Canadian naturalist, found breeding Ospreys to be "generally distributed" in Georgian Bay, Lake Huron. By the 1960s Ospreys had vanished from this area as a breeding bird. In 1973 a single pair built a nest on top of a hydro pole, and by 1993 the Georgian Bay population had grown to over 50 pairs. Similar recovery patterns were seen in other parts of the Great Lakes. What caused these birds to disappear, and why were they able to recolonise?????????????????????????????
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os002
By the 1960s and early 1970s, birds and other aquatic wildlife on the Great Lakes were experiencing reproductive problems. Fish-eating birds, such as the Osprey, are exposed to toxic contaminants in the Great Lakes, through the fish they eat. Since the early 1970s biologists have studied birds in the Great Lakes basin, in order to monitor the levels and biological effects of
toxic chemicals. Since these birds are at the top of the aquatic food web, they can serve as barometers or indicators of environmental conditions........
os003
Ospreys are spectacular and unique birds at the top of the aquatic food web. They are birds of prey, like eagles, hawks and falcons, and have powerful sharp talons and a hooked beak for handling their prey. Unlike their relatives Ospreys eat fish almost exclusively. They catch fish in a dramatic way - diving into the water from a height of up to 40 metres. The opposable outer toe (which can be moved to point forwards or backwards), and the sharp spines on the soles of the feet, help the Osprey to grasp the wriggling fish
until a safe perch is reached. Ospreys are large birds, weighing 1.5 - 2.0 kg, with a wingspan of 1.6 metres. Males are slightly smaller than females.
There is only one species in the Osprey family (Pandionidae), but it inhabits most parts of the world, except the polar regions. Ospreys breed commonly in parts of North America and most of these birds migrate up to 8000 km to wintering areas in South or Central America. Populations breeding in Florida, California and parts of Central America and the Caribbean are non-migratory. Canada supports at least one third of the world's breeding Ospreys. Some
nest close to saltwater, often in loose colonies, but most nest as scattered pairs throughout the vast network of freshwater lakes and rivers in the interior.
Ospreys are present on Canadian breeding areas from early April to September. Their large stick nest is usually built at the top of dead tree close to or over water. Ospreys are adaptable birds, often tolerant of humans, and will nest on a variety of artificial structures such as hydro poles, duck blinds, microwave towers and navigation light towers. In the Great Lakes basin the Osprey's clutch of three eggs is laid in late April or early May, about
three weeks after the birds arrive, and is incubated for about 40 days. Osprey chicks usually fledge in mid-July when they are about 55 days old, but remain around the nesting areas for another three weeks or so, dependent on the parents for food.
Male Ospreys provide virtually all the fish for the family while the females remain at the nest for much of the summer. In the Great Lakes region a variety of fish species are eaten, probably reflecting local availability. Raccoons are the main predator of Osprey eggs, and Great Horned Owls (Bubo virginianus) sometimes kill Osprey chicks and even adults.
Canadian Ospreys spend their first two years of life in Central or South America, and do not usually make their first breeding attempt until three to five years of age. Surprisingly, although Ospreys are long-distance migrants, the young birds normally return to breed within 50 km of their natal site. Colonisation of new areas is therefore relatively slow.
On average, just over 50 per cent of Ospreys die in their first year of life. About 10 to 15 per cent of adults die each year, giving an average adult life expectancy of six to ten years. However, a few have reached the ripe old age of 25 years. In order for a population to sustain itself the number of recruits into the breeding pool must balance the losses due to adult mortality. In
parts of the northeastern United States, biologists have calculated that a pair of Ospreys must produce, on average, 0.8 young each year, for a population to remain stable. This break-even figure will vary with factors such as the availability of suitable nest sites, age at first breeding and mortality rates.................................................
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os004
The earliest records of Ospreys from the Canadian Great Lakes are bones found by archaeologists in native sites on Lake Huron, which were occupied during the 16th century. Towards the end of the 19th century Ospreys could be found throughout much of Ontario, except the extreme southwest where many shorelines had already been cleared of large trees, and they bred commonly around Lake Superior, Lake Huron, and probably also along parts of the Lake Ontario and Lake Erie shorelines.
By the 1930s some declines were noticed, especially around the lower Great Lakes. Removal of the larger pine trees for timber probably reduced the number of suitable nest sites for Ospreys and, like many large birds earlier this century, Ospreys were often shot. Unlike the situation in Europe, egg collectors and trophy hunters in North America appear to have had relatively little impact on Osprey breeding numbers.
These earlier population declines were probably fairly slow and small. They were overshadowed by the dramatic decreases which occurred between the 1940s and 1970s around the Great Lakes. Ornithologists in different regions described Osprey population declines with phrases like "alarming change", and "only a few remain, a sad remnant". Similar population crashes were seen during this period in populations of the Double-crested Cormorant
(Phalacrocorax auritus), another fish-eating bird nesting around the Great Lakes.....................
os005
By the 1960s and early 1970s, birds and other aquatic wildlife on the Great Lakes were experiencing reproductive problems. Fish-eating birds, such as the Osprey, are exposed to toxic contaminants in the Great Lakes, through the fish they eat. Since the early 1970s biologists have studied birds in the Great Lakes basin, in order to monitor the levels and biological effects of
toxic chemicals. Since these birds are at the top of the aquatic food web, they can serve as barometers or indicators of environmental conditions.
The first indications that North American Ospreys were experiencing reproductive problems came from New England in the mid-1960s. Few chicks were being produced and when nests were examined they often contained unhatched or cracked eggs, or just eggshell fragments. The same phenomena were seen in Ospreys around the Great Lakes basin.
In the 1960s and early 1970s Ospreys in the Great Lakes drainage basin were producing, on average, 0.4 to 0.7 chicks per pair each year. This was below the productivity determined by biologists to maintain a stable population (0.8 chicks). Ospreys nesting along the Great Lakes shorelines showed the most significant impacts. Between 1964 and 1971 Ospreys nesting in inland parts of northern Michigan produced an average of 0.6 young per pair, whereas those nesting within five km of the Great Lakes shoreline produced only 0.3 young. Furthermore, Great Lakes Osprey eggs collected during the 1960s and 1970s had significantly thinner shells than those collected before World War II. Some showed over 20 per cent
eggshell thinning......................
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os006
Residues of some organochlorine pesticides and polychlorinated biphenyls (PCBs) are particularly toxic to wildlife. These toxic compounds are lipophilic - attracted to fat molecules, becoming chemically bound to them. The toxic chemicals will then accumulate in an individual organism through a process known as bioaccumulation. Once absorbed by plankton in the water, these
organochlorine molecules work their way up the trophic levels of the food web, from small plankton to large plankton, to crustaceans and other invertebrates, to small fish, and finally to larger predatory fish and fish-eating species like Ospreys, gulls, terns, cormorants, or humans. At each step in the food web the organochlorine contaminant remains bound to lipid molecules, but becomes more concentrated, by a process known as biomagnification. Through this process, minuscule concentrations of toxic chemicals in the water become concentrated in the bodies of wildlife, often
ending up at very high concentrations in organisms at the top of the food web..................C
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DDE and Eggshell thinning
Thinning of eggshells was the first reproductive problem related to contaminants identified in fish-eating birds on the Great Lakes. Eggshell thinning is caused by the presence of DDE in female birds. Eggshells are made of calcium carbonate, which is synthesised from calcium and carbon dioxide in the bird
s body.  This chemical reaction is assisted by the activity of an enzyme, and DDE inhibits the action of this enzyme. As a result, the eggshell does not contain as much calcium carbonate as it should, and so is thinner than normal and more prone to breakage during incubation by the
adult. The density of pores in the eggshell (through which moisture and gases pass) is also altered by DDE contamination of females.
Birds of prey are amongst the most sensitive of species to the effects of DDE. In the United States during the 1970s, the thickness of Osprey eggs was significantly associated with their DDE content. On average, 10 per cent eggshell thinning was associated with two ppm (wet weight) DDE, 15 per cent with four ppm, and 20 per cent with nine ppm DDE. Osprey eggs more than 15
per cent thinner than normal are very likely to break before they hatch, so the critical level of DDE in Osprey eggs appears to be about four ppm..................
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YM_BeenHere
Dichlorodiphenyldichloroethylene (DDE) is a "metabolite" (or a breakdown product in an organism
s body) of the synthetic pesticide known as dichlorodiphenyltrichloroethane (DDT). DDE is produced in most animals when the body tries to rid itself of DDT.
DDT was introduced for widespread use as an insecticide just after World War II. Most uses of DDT were banned in Canada in 1974, under the Pesticide Control Act. However, the use and sale of existing stocks of DDT products were allowed until Dec. 31, 1990. DDT use in the United States was banned in 1972. It is the levels of DDE, and not DDT, which are routinely measured, because DDE is the most fat-soluble of the DDT breakdown products. DDE is also the most easily measured in the fat of animals or their eggs. Unfortunately, DDT is still used quite widely in parts of Central and South America as an effective control measure for malaria and various
insect pests of crops.............
osddea
Dichlorodiphenyldichloroethylene (DDE) is a "metabolite" (or a breakdown product in an organism
s body) of the synthetic pesticide known as dichlorodiphenyltrichloroethane (DDT). DDE is produced in most animals when the body tries to rid itself of DDT.
DDT was introduced for widespread use as an insecticide just after World War II. Most uses of DDT were banned in Canada in 1974, under the Pesticide Control Act. However, the use and sale of existing stocks of DDT products were allowed until Dec. 31, 1990. DDT use in the United States was banned in 1972. It is the levels of DDE, and not DDT, which are routinely measured, because DDE is the most fat-soluble of the DDT breakdown products. DDE is also the most easily measured in the fat of animals or their eggs. Unfortunately, DDT is still used quite widely in parts of Central and South America as an effective control measure for malaria and various
insect pests of crops.............
toxics
97030410351943546165938119
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os008
A wide range of toxic chemicals is found in the water, sediments and aquatic life of the Great Lakes. Some of these persistent contaminants originated from industrial sources within the Great Lakes basin prior to strengthening and enforcing regulations to control discharges into the environment. Due to bans placed on toxic substances such as DDT and mirex, concentrations of toxic contaminants have declined. Today, atmospheric deposition is
another significant source of toxic chemicals in the Great Lakes with toxic pollutants carried from sources well outside the Great Lakes basin. Many of these chemicals break down very slowly in the environment, making their impact a concern many years after they have been withdrawn from use...........
os009
An Osprey egg provides a snapshot of the toxic contaminants present in the female's body at the time the egg was formed. Chemical analysis of eggs from parts of North America in which Ospreys were reproducing poorly in the 1960s and 1970s detected a wide range of organochlorine contaminants. These included the organochlorine pesticide DDT (first used in the mid-1940s), and its breakdown product DDE. Other pesticides such as dieldrin and chlordane compounds, as well as polychlorinated biphenyls (PCBs) and mercury also appeared in Osprey eggs and various body tissues such as
liver, brain and muscle.
Eggs collected in the early 1970s from 20 Osprey nests in northeast Michigan and northwest Ontario contained many of the same contaminants, but for most compounds concentrations were usually below the suspected critical levels. The minimum critical levels of the main contaminants in the eggs of birds of prey (above which adverse reproductive effects are frequently observed) are approximately four ppm for DDE, one ppm for dieldrin, 50 ppm for PCBs, and 0.5 ppm for mercury. However, DDE levels in over two-thirds of these eggs exceeded four ppm - the critical level associated with 15 per cent eggshell thinning and an elevated risk of egg breakage. In other Canadian provinces and territories about three quarters of Osprey eggs analyzed in the 1960s-70s also contained more than four ppm DDE, suggesting that eggshell thinning, and the poor reproduction that resulted, were not confined to the Great Lakes basin.
A single pesticide, DDT, appears to have been largely responsible for the dramatic population declines in Ospreys and many other bird species. Although other toxic chemicals may also have caused biochemical and physiological stress to Ospreys at this time too, their sub-lethal effects are less clearly understood than for DDT.
Not all manufactured chemicals are toxic to wildlife. Many species possess biochemical defence systems which can detoxify some of these foreign substances. However, the organochlorine pesticides and some PCBs are relatively toxic to animals, and birds of prey have relatively inefficient mechanisms for eliminating these lipophilic contaminants................................
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Polychlorinated biphenyls (PCBs) have been in use since 1929. There are 209 PCB isomers (ie. types), which differ from each other in the number and relative position of the chlorine atoms on the biphenyl molecular frame. A small number of these isomers are particularly toxic and are thought to account for the bulk of PCB-induced toxicity in animals.
PCBs are extremely stable molecules, which makes them desirable for industrial uses, but also means that they persist for a long time once released into the environment. The low flammability of PCBs made them useful as lubricating oils and fire retardants in insulating and heat-exchanging fluids used in electrical transformers and capacitors. They also were used as plasticizers and waterproofing agents and in inking processes used to produce carbonless copy paper. Industrial manufacturers voluntarily cut back PCB production in 1971. In Canada, PCB use was regulated in 1977 under the Environmental Contaminants Act. PCBs have not been manufactured in North America since 1978. Importation of all electrical equipment containing PCBs was banned after 1980, and their use was restricted to existing equipment..............tttt
ospcba
Polychlorinated biphenyls (PCBs) have been in use since 1929. There are 209 PCB isomers (ie. types), which differ from each other in the number and relative position of the chlorine atoms on the biphenyl molecular frame. A small number of these isomers are particularly toxic and are thought to account for the bulk of PCB-induced toxicity in animals.
PCBs are extremely stable molecules, which makes them desirable for industrial uses, but also means that they persist for a long time once released into the environment. The low flammability of PCBs made them useful as lubricating oils and fire retardants in insulating and heat-exchanging fluids used in electrical transformers and capacitors. They also were used as plasticizers and waterproofing agents and in inking processes used to produce carbonless copy paper. Industrial manufacturers voluntarily cut back PCB production in 1971. In Canada, PCB use was regulated in 1977 under the Environmental Contaminants Act. PCBs have not been manufactured in North America since 1978. Importation of all electrical equipment containing PCBs was banned after 1980, and their use was restricted to existing equipment.ttttttttttttttttt
ostcdd
YM_BeenHere
Dioxin is the popular name for a class of chlorinated hydrocarbon compounds known as polychlorinated dibenzo-p-dioxins (PCDDs). PCDDs, along with polychlorinated dibenzofurans, or PCDFs, are produced as by-products during some chemical reactions involving high temperatures in the presence of chlorine. Only a few of the 75 PCDD and 135 PCDF isomers are highly toxic; others are practically harmless. The most toxic dioxin is 2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD), but animal species vary considerably in their sensitivity to this chemical.
Elevated levels of 2,3,7,8-TCDD in the environment are linked closely to effluent from previous 2,4,5-trichlorophenol manufacturing (for wood preservatives), and to toxic waste disposal sites associated with this manufacturing, such as Love Canal along the Niagara River. Atmospheric deposition of 2,3,7,8-TCDD, either bound to dry airborne particles, or in rain or snow, is now a major source of this and other organochlorine compounds, particularly in the upper Great Lakes. The original sources of atmospheric PCDDs and PCDFs today include municipal incinerators which burn a wide
range of chlorinated compounds put out with the trash, and exhaust from vehicles burning leaded gasoline or diesel (both of which contain chlorinated hydrocarbon compounds). Chlorine bleaching of kraft wood pulp is another source of 2,3,7,8-TCDD, but this has not been identified as a major source of the compound in the Great Lakes aquatic ecosystem...................................
Mercury is usually found within the natural environment in very small concentrations. Like the organochlorine compounds, it is soluble in fat and blood, breaks down very slowly, and bio-accumulates in the aquatic food web. At low background levels it is not a problem to animals, and birds get rid of mercury in their growing feathers, which are eventually moulted. At higher concentrations mercury is extremely toxic to animals, and
concentrations of only 0.5 ppm in eggs of birds of prey can kill the developing embryo.
Mercury occurs naturally at low concentrations in the environment. However, flooding of large areas of forest (such as during the construction of hydro-electric schemes) causes the release of large quantities of mercury into the aquatic ecosystem. Mercury has been used widely in industrial processes this century, including: ammunition manufacture; machinery manufacture; separation of other metals; the pulp and paper industry; and, as a seed dressing in agricultural areas. In response to growing evidence of chronic and
acute effects in wildlife, the discharge and use of mercury was regulated more tightly in Canada during the 1970s. Mercury is now used, in increasing quantities, in parts of the Amazon basin where prospectors pan for gold along small streams and tributaries. Atmospheric deposition is now a major source of mercury in the Great Lakes ecosystem. 
      
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Mercury is usually found within the natural environment in very small concentrations. Like the organochlorine compounds, it is soluble in fat and blood, breaks down very slowly, and bio-accumulates in the aquatic food web. At low background levels it is not a problem to animals, and birds get rid of mercury in their growing feathers, which are eventually moulted. At higher concentrations mercury is extremely toxic to animals, and concentrations of only 0.5 ppm in eggs of birds of prey can kill the developing embryo.
Mercury occurs naturally at low concentrations in the environment. However, flooding of large areas of forest (such as during the construction of hydro-electric schemes) causes the release of large quantities of mercury into the aquatic ecosystem. Mercury has been used widely in industrial processes this century, including: ammunition manufacture; machinery manufacture; separation of other metals; the pulp and paper industry; and, as a seed dressing in agricultural areas. In response to growing evidence of chronic and
acute effects in wildlife, the discharge and use of mercury was regulated more tightly in Canada during the 1970s. Mercury is now used, in increasing quantities, in parts of the Amazon basin where prospectors pan for gold along small streams and tributaries. Atmospheric deposition is now a major source of mercury in the Great Lakes ecosystem.                     
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The mid-1970s represents a turning point for Ospreys in the Great
Lakes basin, and in other parts of North America. Since 1972, DDT
use had been severely restricted, and Ospreys have been able to
increase their reproductive output to above the break-even point
of 0.8 young per pair. These levels of production have been
sustained generally in many parts of the Great Lakes basin and have
often reached average values of 1.0 - 1.2 young per pair in some
areas. Consequently, Great Lakes Osprey populations have increased
dramatically up to the present day. In the early 1990s, surveys in
all U.S. and some Canadian parts of the Great Lakes basin recorded
at least 750 occupied Osprey nests. The actual population is even
larger since most of northern and central Ontario was not surveyed.
The average annual rates of population increase vary from seven per
cent in northern Michigan and eight per cent in Wisconsin, to 10
to 15 per cent in southern Ontario, and 10 per cent in Upper New
York State. These rates of population increase are very similar to
those seen for Ospreys in other parts of North America which also
were badly affected by DDT. Some former nesting areas around the
shorelines of Lake Huron and Lake Michigan are being recolonised.
Unfortunately, Ospreys have not yet returned to breed along the
lower Great Lakes.
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os011
@	6	A wide range of persistent toxic chemicals is still found in Osprey
eggs and chicks from all parts of the Great Lakes breeding range.
Declining DDE levels since the early 1970s have accompanied
increasing eggshell thickness. Studies in the early 1990s found
very few eggs contained more than four ppm DDE, or had eggshells
more than 10 per cent thinner than those prior to the introduction
of DDT. Broken eggs are no longer a regular sight in Great Lakes
Osprey nests.
Levels of most organochlorine pesticides in Osprey eggs from the
Great Lakes basin have declined over the past 20 years, although
a few eggs today still contain contaminant residues at similar
levels to those seen in the early 1970s. In contrast to other
chemicals, PCB concentrations in eggs have declined only slightly.
Other compounds, such as polychlorinated dibenzo-p-dioxins (PCDDs)
and polychlorinated dibenzofurans (PCDFs), may have much greater
toxicity even though they occur at much smaller concentrations. At
this time the sub-lethal effects of many contaminants are poorly
understood.
Recent studies indicate that most contaminants occur at below
suspected critical levels in Osprey eggs, but eggs and chicks in
Great Lakes nests are usually more highly contaminated than those
further inland. Fish and other fish-eating birds show similar
patterns of geographic variation of these contaminants, suggesting
that Ospreys are accumulating toxic chemicals from the local food
web. In 1992, concentrations of the most toxic PCDD (2,3,7,8-TCDD),
and PCDF (2,3,7,8-TCDF), were generally higher in Osprey eggs from
Lake Huron than from those further inland. Recently, much higher
levels of these compounds have been found in Osprey eggs from the
vicinity of pulp mills in British Columbia, and in eggs of Herring
Gulls and Bald Eagles on the Great Lakes.
Mercury levels have changed relatively little over the past 20
years, and have not exceeded the critical 0.5 ppm level in any
Osprey egg from the Great Lakes basin. Average levels were highest
at Ogoki Reservoir, north of Lake Superior, which had been dammed
after World War II. When reservoirs are created the flooding of
forests results in the release of relatively large quantities of
mercury, contained naturally in trees, into the aquatic environment
as the vegetation decomposes...
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Other factors affecting Great Lakes Ospreys:     
* Humans activities and interventions have assisted the recent
increases in Osprey breeding populations. These increases have
occurred due to restrictions on the use and discharge of DDT and
other toxic chemicals into the environment and through the
construction of stable, artificial platforms for Ospreys on which
to build their nests. Local conservation groups and concerned
individuals, often assisted by government programs to improve
wildlife habitat, have installed a variety of customised nesting
platforms over the past 10 to 15 years. In fact, Osprey platforms
have been so successful in many areas that even the rich and famous
have been placed on a waiting list before they could have one
installed within view of their holiday cottage!    
* In Wisconsin, 67 per cent of the 364 Osprey nests in 1992 were
located on artificial sites, mainly platforms or hydro poles. In
southern Ontario the figure was about 40 per cent. The preferred
larger, older nesting trees found next to the water are now scarce
in many areas, due to extensive selective logging, drainage of
wetlands, and shoreline development. Suitable nesting platforms
built on small rocky islets, or at the edge of cattail stands, have
often been occupied by nesting Ospreys within a year of
installation. This evidence indicates that a shortage of natural
habitat and nesting sites limits population size and breeding range
in parts of the Great Lakes basin. In addition, nests located on
platforms or poles are relatively stable, and less likely to be
blown down. They also are less accessible to predators such as
raccoons.    
* Most importantly, public attitudes towards environmental matters
have shifted dramatically since earlier this century, and most
people now want to watch and protect birds such as Ospreys.    
* There have been major changes this century to fish populations
in the Great Lakes, affecting mostly open-water species such as
alewife, rainbow smelt, walleye, and lake trout. Ospreys feed in
relatively shallow water, usually around one to two metres deep,
consuming warm water species such as pumpkinseed, sunfish, rock
bass, brown bullhead, yellow perch and northern pike. Changes to
open-water fish stocks may not have affected Osprey populations to
the same extent as other fish-eating birds such as gulls, terns and
cormorants.    
* This century, shallow waters and inshore habitats have been
greatly altered due to shoreline developments and general loss of
natural vegetation, especially in the more densely inhabited areas.
Although these changes may have caused the loss of fish spawning
habitat, other changes, such as eutrophication (nutrient enrichment
largely due to fertilizer run-off from farmland), fish stocking,
and damming of lakes, may have actually improved feeding conditions
for Ospreys in some areas.    
* Raccoons are serious predators of Osprey eggs in some areas, and
their numbers and range have been increasing steadily in recent
years. Raccoons will swim out to Osprey nests in shallow lakes, and
even climb 15 metres trees or hydro poles to plunder a clutch.
Sheet metal anti-predator guards at the foot of poles or trees have
proved to be an effective way of reducing such predation.    
* Bald Eagles (Haliaeetus leucocephalus) are usually dominant over
Ospreys, ousting them from nest-sites and stealing fish from them.
Their numbers are slowly recovering, in the Great Lakes basin,
which may lead to Ospreys being forced out of some areas into more
marginal habitats. Unlike Ospreys, however, Bald Eagles are
extremely sensitive to human disturbance near their nests,
especially during the incubation period, and are unlikely to
recolonise Great Lakes shorelines having a high density of cottages
and recreational activity.    
* Weather conditions can have dramatic effects on Osprey
reproduction. Strong winds blow down some nests, particularly those
balanced on dead snags or on flimsy hydro poles in exposed sites.
Heavy rain, low temperatures and strong winds during the early
nestling stage can cause heavy mortality amongst Osprey broods, and
often reduce the male's foraging success. Such conditions occurred
in June and July of 1992 resulting in unusually high nestling
mortality in most parts of the Great Lakes basin.
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os013
Ospreys, like some other animals at the top of the aquatic food
web, seem to have responded quite rapidly to the presence of
certain toxic chemicals in their food. The most obvious effects
have been the eggshell thinning caused by DDE, and subsequent
population declines and local extinctions. The decline of Ospreys
in New England during the 1950s and 1960s was one of the first
signs noticed by naturalists that something was going terribly
wrong in the environment, and this ultimately led to the
identification of DDT in eggs as the main source of the problem.
Only a few years after DDT was banned from use, Ospreys began to
reproduce more successfully, and to recolonise some former breeding
areas in the Great Lakes. When examining DDT levels, the Osprey was
an effective barometer of environmental quality.
Does this recent recovery of the Osprey population indicate a
healthy Great Lakes basin ecosystem? There are still a large number
of persistent toxic chemicals present in Great Lakes Ospreys,
fortunately at lower concentrations than in the 1960s and 1970s.
The biological effects of many of these contaminants are still
poorly understood. Ospreys are still absent as breeding birds from
the lower Great Lakes shorelines, even though suitable nesting and
feeding habitat appears to exist. Only further careful research and
monitoring will allow biologists to explain why.
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os014
Ospreys, like some other animals at the top of the aquatic food
web, seem to have responded quite rapidly to the presence of
certain toxic chemicals in their food. The most obvious effects
have been the eggshell thinning caused by DDE, and subsequent
population declines and local extinctions. The decline of Ospreys
in New England during the 1950s and 1960s was one of the first
signs noticed by naturalists that something was going terribly
wrong in the environment, and this ultimately led to the
identification of DDT in eggs as the main source of the problem.
Only a few years after DDT was banned from use, Ospreys began to
reproduce more successfully, and to recolonise some former breeding
areas in the Great Lakes. When examining DDT levels, the Osprey was
an effective barometer of environmental quality.
Does this recent recovery of the Osprey population indicate a
healthy Great Lakes basin ecosystem? There are still a large number
of persistent toxic chemicals present in Great Lakes Ospreys,
fortunately at lower concentrations than in the 1960s and 1970s.
The biological effects of many of these contaminants are still
poorly understood. Ospreys are still absent as breeding birds from
the lower Great Lakes shorelines, even though suitable nesting and
feeding habitat appears to exist. Only further careful research and
monitoring will allow biologists to explain why.
Three yeard ago sceintists ..   to healthy and productive ecosystems
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	* Government of Canada. 1991. Toxic chemicals in the Great Lakes
and Associated Effects. Environment Canada, Dept. of Fisheries and
Oceans, Health and Welfare Canada: Ottawa.
* Grier, J.W., C.R. Sindelar and D.L. Evans. 1977. Reproduction and
toxicants in Lake of the Woods Ospreys. pp. 181-192 in:
Transactions of the North American Osprey Research Conference,
Virginia, 1972. Edited by J.C. Ogden. US Dept. of the Interior
National Park Service, Transactions and Proceedings Series No. 2.
* McKeane, L. and D. V. Weseloh. 1993. Bringing the Bald Eagle back
to Lake Erie. State of the Environment Fact Sheet No. 93-3.
Environment Canada, Ottawa.
* Noble, D.G. and J.E. Elliott. 1990. Levels of contaminants in
Canadian raptors, 1966 to 1988; effects and temporal trends.
Canadian Field-Naturalist 104: 222-243.
* Poole, A.F. 1989. Ospreys: A Natural and Unnatural History.
Cambridge University Press: Cambridge.
* Postupalsky, S. 1977. Status of the Osprey in Michigan. pp.
153-166 in: Transactions of the North American Osprey Research
Conference, Virginia, 1972. Edited by J.C. Ogden. US Dept. of the
Interior National Park Service, Transactions and Proceedings Series
No. 2.
* Postupalsky, S. 1977. Osprey reproduction in the Lake Nipigon
area. pp. 193-197 in: Transactions of the North American Osprey
Research Conference, Virginia, 1972. Edited by J.C. Ogden. US Dept.
of the Interior National Park Service, Transactions and Proceedings
Series No. 2.
* Postupalsky, S. 1989. Osprey, Chapter 18, pp. 297-313 in: I.
Newton (Ed.), Lifetime Reproduction in Birds. Academic Press:
London.
* Steidl, R.J., Griffin, C.R. & Niles, L.J. 1991. Contaminant
levels of Osprey eggs and prey reflect regional differences in
reproductive success. J. Wildlife Management 55: 601-607.
* Wiemeyer, S.N., C.M. Bunck and A.J. Krynitsky. 1988.
Organochlorine pesticides, polychlorinated biphenyls, and mercury
in Osprey eggs - 1970-79 - and their relationships to shell
thinning and productivity. Archives of Environmental Contamination
and Toxicology 17: 767-787.
* Wiemeyer, S.N., Schmeling, S.K. & Anderson, A. 1987.
Environmental pollutant and necropsy data for Ospreys from the
eastern United States, 1975-1982. Journ. Wildl. Diseases 23:
279-291.
oslita
	* Government of Canada. 1991. Toxic chemicals in the Great Lakes
and Associated Effects. Environment Canada, Dept. of Fisheries and
Oceans, Health and Welfare Canada: Ottawa.
* Grier, J.W., C.R. Sindelar and D.L. Evans. 1977. Reproduction and
toxicants in Lake of the Woods Ospreys. pp. 181-192 in:
Transactions of the North American Osprey Research Conference,
Virginia, 1972. Edited by J.C. Ogden. US Dept. of the Interior
National Park Service, Transactions and Proceedings Series No. 2.
* McKeane, L. and D. V. Weseloh. 1993. Bringing the Bald Eagle back
to Lake Erie. State of the Environment Fact Sheet No. 93-3.
Environment Canada, Ottawa.
* Noble, D.G. and J.E. Elliott. 1990. Levels of contaminants in
Canadian raptors, 1966 to 1988; effects and temporal trends.
Canadian Field-Naturalist 104: 222-243.
* Poole, A.F. 1989. Ospreys: A Natural and Unnatural History.
Cambridge University Press: Cambridge.
* Postupalsky, S. 1977. Status of the Osprey in Michigan. pp.
153-166 in: Transactions of the North American Osprey Research
Conference, Virginia, 1972. Edited by J.C. Ogden. US Dept. of the
Interior National Park Service, Transactions and Proceedings Series
No. 2.
* Postupalsky, S. 1977. Osprey reproduction in the Lake Nipigon
area. pp. 193-197 in: Transactions of the North American Osprey
Research Conference, Virginia, 1972. Edited by J.C. Ogden. US Dept.
of the Interior National Park Service, Transactions and Proceedings
Series No. 2.
* Postupalsky, S. 1989. Osprey, Chapter 18, pp. 297-313 in: I.
Newton (Ed.), Lifetime Reproduction in Birds. Academic Press:
London.
* Steidl, R.J., Griffin, C.R. & Niles, L.J. 1991. Contaminant
levels of Osprey eggs and prey reflect regional differences in
reproductive success. J. Wildlife Management 55: 601-607.
* Wiemeyer, S.N., C.M. Bunck and A.J. Krynitsky. 1988.
Organochlorine pesticides, polychlorinated biphenyls, and mercury
in Osprey eggs - 1970-79 - and their relationships to shell
thinning and productivity. Archives of Environmental Contamination
and Toxicology 17: 767-787.
* Wiemeyer, S.N., Schmeling, S.K. & Anderson, A. 1987.
Environmental pollutant and necropsy data for Ospreys from the
eastern United States, 1975-1982. Journ. Wildl. Diseases 23:
279-291.
osunits
9703041048065121934177116658
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Units of Toxic Contaminants
The concentrations of toxic chemicals in the environment are often expressed in parts per million (ppm). When dealing with bird eggs, the concentrations are usually given relative to the weight of the liquid part
of the egg - its 'wet weight'. Therefore, ppm (wet weight) is the number of
grams of contaminant per one million grams of egg contents. To help you
picture how small some of these concentrations are, one part per million is
equivalent to a cube of ice (5 g) in a five tonne block of ice. Unfortunately, some chemicals are harmful to wildlife even at these very low levels.....q
osunitsa
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Units of Toxic Contaminants
The concentrations of toxic chemicals in the environment are often
expressed in parts per million (ppm). When dealing with bird eggs, the
concentrations are usually given relative to the weight of the liquid part
of the egg - its 'wet weight'. Therefore, ppm (wet weight) is the number of
grams of contaminant per one million grams of egg contents. To help you
picture how small some of these concentrations are, one part per million is
equivalent to a cube of ice (5 g) in a five tonne block of ice.
Unfortunately, some chemicals are harmful to wildlife even at these very
low levels.
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